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Original scientific paper

THE INFLUENCE OF POLYACRYLAMIDE (PAA) ON HYDROGEN EVOLUTION REACTION AT THE POLYCRYSTALLINE GOLD

By
D. Ĉamovska ,
D. Ĉamovska

Faculty of Technology and Metallurgy, Saints Cyril and Methodius University of Skopje , Skopje , North Macedonia

M. Cvetkovska ,
M. Cvetkovska

Faculty of Technology and Metallurgy, Saints Cyril and Methodius University of Skopje , Skopje , North Macedonia

T. Grčev
T. Grčev

Faculty of Technology and Metallurgy, Saints Cyril and Methodius University of Skopje , Skopje , North Macedonia

Abstract

The influence of polyacrylamide (PAA; Mn between 5∙103 and 1.5∙106 gmol-1 ) on hydrogen evolution reaction at the polycrystalline gold in 0.5 M H2SO4 was studied using potentiodynamic measurements (5 mV/s) in the potential range from 0 to -0.6 V/she. It was concluded that formation of protective layer of PAA, adsorbed on the electrode surface, is responsible for inhibition of hydrogen evolution reaction. The further investigations, especially on iron and steel in acid solutions (real corrosion system) confirm the effective inhibition of corrosion by PAA.

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Authors retain copyright. This work is made freely available online under an open-access model under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License (CC-http://creativecommons.org/licenses/by-nc-nd/4.0/BY-NC-ND 4.0).

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