Physical and chemical modification of lignocellulosic waste biomass-tool for improving sorption capacity

  • Zorica Lopicic Institute for Technology of Nuclear and Mineral Raw Materials, Belgrade, Serbia
  • Tatjana Šoštarić Institute for Technology of Nuclear and Mineral Raw Materials, Belgrade, Serbia
  • Jelena Milojković Institute for Technology of Nuclear and Mineral Raw Materials, Belgrade, Serbia
  • Marija Mihajlović Institute for Technology of Nuclear and Mineral Raw Materials, Belgrade, Serbia
  • Jelena Petrović Institute for Technology of Nuclear and Mineral Raw Materials, Belgrade, Serbia
  • Ivan Antanasković Investfarm-Impex doo, Beograd, Serbia
  • Mirjana Stojanović Institute for Technology of Nuclear and Mineral Raw Materials, Belgrade, Serbia
DOI: https://doi.org/10.7251/JEPM1810034L

Abstract

The main constituents of ligno-cellulosic (LC) biomass are lignin, celluloses and hemicelluloses, complex polymers with many functional groups, which can be modified with the purpose to improve the sorption properties of the starting material. This paper presents several physical and chemical modifications applied to LC biomass of peach stones (Prunus persica L.), abundant waste from food industry. These stones were firstly mechanically activated in two mill types, and then by different chemicals. Sorption experiments were performed in batch reaction system with stirring. Cu(II) sorption kinetic was tested through three reaction kinetic models: pseudo-first order, pseudo-second order and Elovich equation. FT-IR analyses of chemically modified samples is also presented and discussed.


Keywords: peach stones, modification, sorption, kinetics, FT-IR

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References

  • Allouche, F.N., Mameri, N., Guibal, E., 2011. Pb(II) biosorption on Posidonia oceanica Chemical Engineering Journal, 168, 1174–1184. https://doi.org/10.1016/j.cej.2011.02.005

  • Blázquez, G., Calero, M., Martínez, C., Cotes, M.T., Ronda, A., Martín-Lara, M.Á. (2014). Characterization and modeling of pyrolysis of the two-phase olive mill solid waste. Fuel Processing Technology, 126, 104–111. https://doi.org/10.1016/j.fuproc.2014.04.020

  • Febrianto, J., Kosasih, A.N., Sunarso, J., Ju, Y.H., Indraswati, N., Ismadji, S. (2009). Equilibrium and kinetic studies in adsorption of heavy metals using biosorbent: A summary of recent studies. Journal of Hazardous Materials, 162, 616–645. https://doi.org/10.1016/j.jhazmat.2008.06.042

  • Ho, Y.S., McKay, G., 1999. Pseudo-second order model for sorption processestle. Process Biochemistry,. 34, 451–465. https://doi.org/10.1016/S0032-9592(98)00112-5

  • Iqbal, M., Saeed, A., Zafar, S.I. (2009). FTIR spectrophotometry, kinetics and adsorption isotherms modeling, ion exchange, and EDX analysis for understanding the mechanism of Cd2+ and Pb2+ removal by mango peel waste. Journal of Hazardious Materials, 164, 161–171. https://doi.org/10.1016/j.jhazmat.2008.07.141

  • Kragović, M. (2014). Uklanjanje jona olova iz vodenih rastvora upotrebom prirodnog i Fe(III)- modifikovanog zeolita. Doktorska diserta cija. Fakultet za fizičku hemiju. Univerzitet u Beogradu.

  • Lagergren, S., Svenska, K., 1898. About the theory of so called adsorption of soluble substances. Veternskapsakad Handl. 24, 1–39.

  • Lopičić, Z. (2017). Proučavanje sorpcionog i energetskog potencijala Prunuis persica L., Doktorska disertacija, Tehnološko-metalurški fakultet, Univerzitet u Beogradu.

  • Lopičić, Z., Milojković, J., Šoštarić, T., Petrović, M., Mihajlović, M., Lačnjevac, Č., Stojanović, M. (2013). Influence of pH value on Cu(II) biosorption by lignocellulose peach shell waste material. Hemijska Industrija, 67, 1007–1015. https://doi.org/10.2298/HEMIND121225018L

  • Lopičić, Z.R., Stojanović, M.D., Kaluđerović Radoičić, T.S., Milojković, J. V., Petrović, M.S., Mihajlović, M.L., Kijevčanin, M.L.J. (2017). Optimization of the process of Cu(II) sorption by mechanically treated Prunus persica L. - Contribution to sustainability in food processing industry. Journal of Cleaner Produstion, 156, 95–105. https://doi.org/10.1016/j.jclepro.2017.04.041

  • Lopičić, Z.R., Stojanović, M.D., Marković, S.B., Milojković, J.V., Mihajlović, M.L., Kaluderović Radoičić, T.S., Kijevčanin, M.L.J. (2016). Effects of different mechanical treatments on structural changes of lignocellulosic waste biomass and subsequent Cu(II) removal kinetics. Arabian Journal of Chemistry. https://doi.org/10.1016/j.arabjc.2016.04.005

  • Low, M.J.D., 1960. Kinetics of Chemisorption of Gases on Solids. Chemical Review, 60, 267–312. doi: https://doi.org/10.1021/cr60205a003

  • Marković, S., Stanković, A., Lopičić, Z., Lazarević, S., Stojanović, M., Uskoković, D., (2015). Application of raw peach shell particles for removal of methylene blue. Journal of Environmental Chemical Engineering, 3, 716–724. https://doi.org/10.1016/j.jece.2015.04.002

  • Martín-Lara, M.A., Blázquez, G., Ronda, A., Pérez, A., Calero, M., 2013. Development and Characterization of Biosorbents To Remove Heavy Metals from Aqueous Solutions by Chemical Treatment of Olive Stone. Industrial and Engineering Chemistry Research, 52, 10809–10819. https://doi.org/10.1021/ie401246c

  • Parlayici-Karatas, S., Pehlivan, E. (2012). Removal of hexavalent chromium using modified pistachio shell. Advances in Environmental Research, 1, 167–179. https://doi.org/10.12989/aer.2012.1.2.167

  • Rahman, S.H.A., Choudhury, J.P., Ahmad, A.L., 2006. Production of xylose from oil palm empty fruit bunch fiber using sulfuric acid. Biochemical Engineering Journal, 30, 97–103. doi: https://doi.org/10.1016/j.bej.2006.02.009

  • Ravindran, R., Jaiswal, A.K. (2015). A Comprehensive Review on Pre-treatment Strategy for Lignocellulosic Food Industry Waste: Challenges and Opportunities. Bioresource Technology, 199, 92-102. 1016/j.biortech.2015.07.106

  • Torab-Mostaedi, M., Asadollahzadeh, M., Hemmati, A., Khosravi, A. (2013). Equilibrium , kinetic , and thermodynamic studies for biosorption of cadmium and nickel on grapefruit peel. Journal of the Taiwan Institute of Chemical Engineers, 44, 294–302. https://doi.org/10.1016/j.jtice.2012.11.001

  • Wahab, M.A., Jellali, S., Jedidi, N., 2010. Ammonium biosorption onto sawdust: FTIR analysis, kinetics and adsorption isotherms modeling. Bioresource Technology, 101, 5070–5075. https://doi.org/10.1016/j.biortech.2010.01.121

  • Wu, F.C., Tseng, R.L., Juang, R.S., 2009. Characteristics of Elovich equation used for the analysis of adsorption kinetics in dye-chitosan systems. Chemical Engineering Journal, 150, 366–373. https://doi.org/10.1016/j.cej.2009.01.014
    • Published
    2018-07-11
    How to Cite
    LOPICIC, Zorica et al. Physical and chemical modification of lignocellulosic waste biomass-tool for improving sorption capacity. Journal of Engineering & Processing Management, [S.l.], v. 10, n. 1, p. 34-41, july 2018. ISSN 2566-3615. Available at: <https://jepm.tfzv.ues.rs.ba/index.php/Journal/article/view/189>. Date accessed: 25 jan. 2020. doi: https://doi.org/10.7251/JEPM1810034L.
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    Vol 10 No 1 (2018): Journal of Engineering & Processing Management
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