Original scientific paper

SYNTHESIS AND STRUCTURAL ANALYSIS OF A Cu(II) COMPLEX WITH PYRIDOXAL S-METHYLISOTHIOSEMICARBAZONE (PLITSC) LIGAND

Authors

• • S. Ivković
  • Educons University, Sremska Mitrovica, Faculty of Environmental governance and corporate responsibility, Serbia
• • V. Jevtović
  • University of Novi Sad, Novi Sad, Faculty of Sciences, Department of Chemistry, Serbia

Abstract

Reaction between a warm water mixture of pyridoxal hydrochloride (PL.HCl), and Smethyilisothiosemicarbazidehydroiodide (SMeTSC.HI) in the presence of Na2CO3 10 H O, we got pyridoxal S-methylisothiosemicarbazone (PLITSC; H2L). Ligand with appropriate Cu salt is coordinated, to give next complex: dark-brown, penta coordinated, square-pyramidal structure, mono(ligand)complex Cu(II) formula, [Cu(PLITSC)Br(CH3OH)]Br. In this work is given synthesis and structure of the complex with Schiff-based ligand.

Keywords: Pyridoxal-S-methylisothiosemicarbazone, Cu(II) complex, Synthesis, Crystal structure

How to Cite: Ivković, S. & Jevtović, V. (2010) “SYNTHESIS AND STRUCTURAL ANALYSIS OF A Cu(II) COMPLEX WITH PYRIDOXAL S-METHYLISOTHIOSEMICARBAZONE (PLITSC) LIGAND”, Journal of Engineering & Processing Management. 2(2).